No. The USB 3.0 port is for connecting and sharing USB drives only. It does not support peripherals like printers, scanners, or cameras.
Use it only for local file sharing via a USB drive. The port does not support FTP, media servers, or virtualUSB.
If you need network printing, connect the printer directly to a computer on the network and share it, or use a printer with built-in Ethernet or Wi-Fi and connect it to your Velop network.